"The Superhero Secret" Ash and his friends fall into a trap set by Team Rocket, causing Togepi to be in danger. Luckily for them, Togepi is saved by a superhero who called himself Gligar and his pokemon, a gligar. Later Ash and co. find out who he is and settles an argument between father and daughter.

"Mild 'n Wooly" Ash and friends meet a young girl with a mareep called Fluffy. Along with her mother, who happened to own a raichu, they foil another one of Team Rocket's plans to capture all the mareep that they own.

"Wired for Battle" Ash and friends meet Mr. Morramasa, who owns a Scizor, and runs a training school for pokemon trainers and their pokemon. Ash challenges Shingo, Mr. Morramasa's top student, who thinks that his computer is more important than pokemon. Ash beats him with his heracross, and Shingo realizes that his computer isn't everything.
This is my favorite episode on this DVD, probably because Ash and Shingo has a very long pokemon battle.